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VOL. 2, ISSUE 4 (2017)
Redox reactions of cobalt (III) Complexes of α-hydroxy acids by quinolinium chloro chromate (QCC) in Surfactants
Authors
K Murali, M Shreelekha, B Divya
Abstract
The kinetics of one electron transfer mode seems to be unavailable for QCC with Cobalt (III) bound and unbound complexes of α-hydroxy acids in surfactant medium, QCC oxidizes Cobalt (III) bound and unbound α- hydroxyl acids. It rules out the synchronous C-C bond fission and electron transfer to Cobalt (III) centre. Oxidation of above complexes increases with increase in temperature. The increase in the rate is observed with increase in the concentration of the surfactant. The added DDAC enhances the rate of oxidation of a reaction much more than Polysorbate 80. Similar trends has been observed in lactato, glycolato and Mandelato Co (III) complexes.
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Pages:102-107
How to cite this article:
K Murali, M Shreelekha, B Divya "Redox reactions of cobalt (III) Complexes of α-hydroxy acids by quinolinium chloro chromate (QCC) in Surfactants". International Journal of Research in Pharmacy and
Pharmaceutical Sciences, Vol 2, Issue 4, 2017, Pages 102-107
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